| 학회 |
한국고분자학회 |
| 학술대회 |
2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
41권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Non-catalyst Polymerization of Ethynylpyridines using Sodium 4-(2-bromoethyl)benzenesulfonate |
| 초록 |
Sodium salts and acid forms of such conducting polymers as poly(3-thiophene ethanesulfonate) and poly(3-thiopphene butanesulfonate) were the important examples of self-doped conducting polymers to show water solubility in neutral and doped states. After then, there had been a number of report concerning the synthesis of conjugated polymers with various sulfonate groups. Here a new ionic polyacetylene with the sulfonate groups was synthesized through the non-catalyst polymerization of 2-ethynylpyridine using sodium benzenesulfonate derivatives. Instrumental analysis data revealed that the polymer had the fully conjugated backbone system with the designed substituents. The electro-optical and electrochemical properties of polymer were also studied. |
| 저자 |
제갈영순1, 진성호2, 박종욱3, 심상연4, 임권택5, 김상율6
|
| 소속 |
1경일대, 2부산대, 3가톨릭대, 4강릉원주대, 5부경대, 6한국과학기술원 |
| 키워드 |
non-catalyst; polymerization; benzenesulfonate; self-doping; characterization
|
| E-Mail |
|
