화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2015년 가을 (10/21 ~ 10/23, 일산 KINTEX)
권호 21권 2호, p.2330
발표분야 환경
제목 Study on CO₂ desorption behavior of amine-functionalized silica for CO₂ capture
초록 Amine-silica adsorbent which is a part of the array of hybrid organic-inorganic dry sorbent for CO2 capture is one of the emerging technologies of Carbon Capture and Sequestration (CCS) to mitigate climate change. Development of this type of sorbent and design of process condition tend to be very critical as several issues arise upon realization of its large-scale implementation. Since one of the desirable characteristics of a CO2 sorbent is long term stability under a range of practical operating condition, study of CO2 desorption behaviors can be beneficial in the selection of the desorption condition upon implementation of these sorbents in commercial capturing process. In this study, desorption behavior of amine-functionalized silica sorbents prepared through incipient wetness technique with primary, secondary and di-amino organosilanes were investigated using Thermogravimetric analysis (TGA) and Temperature Programmed Desorption (TPD). Furthermore, in-situ IR was used to evaluate adsorbed and desorbed species formed at different temperature.
저자 고영수, 전재완, 박종현, Jhulimar Celedonio
소속 공주대
키워드 amine-functionalized silica; CO2 adsorption; CO2 desorption; FT-IR; stability
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