| 학회 |
한국공업화학회 |
| 학술대회 |
2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터) |
| 권호 |
17권 2호 |
| 발표분야 |
포스터-촉매 |
| 제목 |
Poly-Si 생산을 위한 STC hydrochlorination 촉매 반응 연구 |
| 초록 |
Hydrogenation of silicon tetrachloride (SiCl4) to trichlorosilane (SiHCl3) using carbon-based catalysts is studied. The results show that surface functional groups that result from the defect sites of the carbon catalysts play an important role in producing SiHCl3. Because the metal-carbon composites obtained by treating sucrose and transition metals at high temperature in the N2 flow have more defect sites, they display an increased SiHCl3 yield. Elemental analysis of the catalyst and reaction results demonstrate that there is a very good correlation between the SiHCl3 yield and the amount of deposited silicon during the induction time, and the SiHCl3 yield and the accumulated amount of deposited Si species rapidly change initially and then reach a stable value. Hydrogenation of SiCl4 to SiHCl3 in metal-grade silicon (mg-Si) powder is known to give a higher equilibrium conversion of SiCl4. |
| 저자 |
이우형1, 박용기1, 최원춘1, 한주희2, 이동호2, 안귀룡2, 김길호2
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| 소속 |
1한국화학(연), 2한화케미칼 |
| 키워드 |
Poly-Si; STC; TCS; MG-Si
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| E-Mail |
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