화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 봄 (04/23 ~ 04/25, 제주ICC)
권호 14권 1호, p.50
발표분야 고분자
제목 Conducting Core-Shell Poly(Styrene/Pyrrole) Latex Particles Prepared by Fe3+-Catalyzed Oxidative Polymerization during Emulsifier-Free Emulsion Polymerization
초록 It was demonstrated that core-shell poly(styrene/pyrrole) latex particles were successfully prepared by oxidative polymerization with emulsifier-free emulsion polymerization. The size of core-shell poly(styrene/pyrrole) latex particles could be controlled according to the concentration of NaSS. The core-shell structure and size of the resulting latex particles according to concentration of NaSS were proved by SEM and TEM analysis. Surface charge of the latex particles was changed according to the concentration of NaSS and measured by Zeta-potential analysis. The resulting latex particles showed high conductivity after doping and drying. This new strategy is universal for the synthesis of many other conjugated materials or composite particles with controlled morphology. These morphology controlled conjugated polymer composite particles (i.e., core-shell particles) may have potential practical applications in various electrical devices and sensors.
저자 이동규, 이정민, 김중현
소속 연세대
키워드 Conducting polymer; Polypyrrole; Core-Shell; Oxidative polymerization; Emulsifier-free emlusion polymerization
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