| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center)) |
| 권호 |
21권 1호 |
| 발표분야 |
정밀화학 |
| 제목 |
Synthesis and Photoelectronic Properties of Porphyrin Derivatives with Electron Donor-Acceptor Group at Meso-position Aimed for Bulk Heterojunction Organic Solar Cells |
| 초록 |
A series of porphyrin derivatives with the electron-donating or accepting groups at meso-position were designed and synthesized for the effective mediation of photoelectron transfer in bulk heterojunction organic solar cells. Using MacDonald-type [2+2] condensation of the dipyrolomethane and corresponding aldehyde, AB2C-type symmetric porphyrins were prepared and their photoelectronic properties were studied based on UV-Vis and luminescence spectra and CV data. The absorptions of those were observed at near 420 nm with Q-band peaks(510-650 nm) in chloroform. Two emissions were observed at 650, 710 nm. The band gap of porphyrins was calculated as 1.8eV. |
| 저자 |
황광진 |
| 소속 |
홍익대 |
| 키워드 |
porphyrin; organic solar cell
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| E-Mail |
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