화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2007년 가을 (11/02 ~ 11/03, 한경대학교)
권호 11권 2호
발표분야 정밀화학
제목 Stereodivergent approach to syn and anti isomers of γ-amino-β-hydroxy acids: (3S,4S)- and (3R,4S)-AHPPA derivatives
초록 A stereodivergent approach, controlled by N-hydroxymethyl group via intramolecular conjugate addition and intramolecular epoxidation reaction, has been developed to obtain (3S,4S)-AHPPA and (3R,4S)-AHPPA derivatives stereoselectively. Selectivity of the intramolecular conjugate addition was more than 10 to 1 and that of intramolecular epoxidation was more than 20 to 1.
저자 강은실, 김영규, 송지윤, 유동원, 강문성
소속 서울대
키워드 AHPPA; N-hydroxymethyl group; intramolecular conjugate addition; intramolecular epoxidation
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