| 학회 | 한국공업화학회 |
| 학술대회 | 2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 | 19권 1호 |
| 발표분야 | 에너지저장변환_포스터 |
| 제목 | Alternating Electron Donor-Acceptor Conjugated Polymer based on Quinacridone and Quinoxaline for Organic Photovoltaics |
| 초록 | The characteristics of organic photovoltaics (OPVs) such as low cost, flexibility and fabrication by solution processes have made OPVs a unique member of the solar cell family. Research on developing new materials mainly focuses on the synthesis of new donor-acceptor (D-A) type small band gap polymers that can harvest more sun light to generate higher short-circuit current density (JSC). A quinacridone (QC) which is known as a red-violet pigment, has an ordered structure, self-assembled characteristics and high hole mobility. A quinoxaline (Qx) moiety acts as strong acceptors due to the presence of two imine nitrogen atoms, which has octyloxy chains at the meta-positon (m8) of the phenyl ring for solubility. Moreover, introducing thiophene (T) spacer between D and A unit as π-bridge is extended π-conjugation lengths. In this study, we synthesized D-A type copolymer using quinacridone as the D-unit with m8-quinoxaline as the A-unit by Suzuki coupling reaction. This polymer is showed physical, optical, electrochemical and photovoltaic properties. |
| 저자 | 황규효, 김두헌, 한용운, 문두경 |
| 소속 | 건국대 |
| 키워드 | Organic Photovoltaics; Conjugated polymer; Quinacridone; Quinoxaline |
