| 학회 |
한국화학공학회 |
| 학술대회 |
2012년 봄 (04/25 ~ 04/27, 제주 ICC) |
| 권호 |
18권 1호, p.1172 |
| 발표분야 |
촉매 |
| 제목 |
Synthesis of glycerol carbonate from urea and glycerol over metal oxide catalysts |
| 초록 |
The influences of acid–base properties of metal oxides on the catalytic performance for synthesis of glycerol carbonate from urea and glycerol was investigated. CaO, La2O3, MgO, ZnO, ZrO2, and Al2O3 were used as catalysts. Among the catalysts, amphoteric ZnO showed the best catalytic activity toward glycerol carbonate. It might be due to a balanced bifunctional acid–base property of ZnO where the Lewis acid activates the carbonyl of the urea and the conjugated basic site activates the hydroxyl group of the glycerol. Based on the experiential investigation, the reaction conditions over ZnO for a batch process were optimized, and the highest glycerol carbonate yield was attained (based on urea) to 66%. |
| 저자 |
김철웅1, 김윤민1, 김한규1, 정광은1, 김태완1, 채호정1, 정순용1, 이관영2
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| 소속 |
1한국화학(연), 2고려대 |
| 키워드 |
글리세롤카보네이트; 글리세롤; 요소; 산화물 촉매
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| E-Mail |
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| 원문파일 |
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