화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.2770
발표분야 생물화공
제목 Enzymatic synthesis of butyl butyrate and kinetic analysis
초록 Butyl butyrate is used in the flavor and food industry to create sweet fruity flavors that are similar to pineapple. This study investigated enzymatic synthesis of butyl butyrate by esterification of butyric acid and butanol using Novozym 435 (Candida antarctica lipase B immobilized on macroporous polyacrylate resin) in heptane. Enzymatic reactions were conducted in aqueous or organic media, and butyl butyrate productivities were compared in each medium condition. Butyl butyrate was excellently synthesized in organic medium, heptane, at 50 oC and butyl butyrate conversion efficiency was over 95 % in fed-batch small-scale reactor (125 ml). The kinetics of esterification to butyl butyrate was mathematically analyzed to show the inhibition levels of the reaction products, butyl butyrate and H2O.
저자 안지혜1, 김병천1, 엄영순1, 오민규2, 상병인1
소속 1한국과학기술(연), 2고려대
키워드 Enzyme; butyl butyrate; kinetics
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