화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2022년 봄 (04/20 ~ 04/23, 제주국제컨벤션센터)
권호 28권 1호, p.437
발표분야 [주제 7] 수소
제목 Influence of different g-C3N4 hydrothermal synthesis conditions on photocatalytic tetracycline degradation under visible light
초록 In this work, metal-free graphitic carbon nitride (g-C3N4) photocatalysts used for the hydrothermal process at different temperatures (180, 200, and 220°C) were synthesized in different atmospheric conditions (air and nitrogen). To evaluate the impact of g-C3N4 hydrothermal synthesis conditions, characterization techniques were used to examine the photocatalysts and photodegradation of tetracycline over the modified g-C3N4 under visible light was investigated. Compared to the bulk g-C3N4 and AT-x the as-prepared samples NT-x possessed a higher specific surface area, increased bandgap value, and significantly improved photogenerated electron-hole separation. As a result, NT-x exceeded bulk g-C3N4 and AT-x in terms of absorption and photocatalytic activity for tetracycline degradation. However, the increase of hydrothermal temperatures also demonstrated the appearance of the breakdown of nanosheets to tri-s-triazine units, which enhanced the absorption capacity but negatively affected the recombination rate of as-prepared samples.
저자 HOANG THI VAN ANH1, Nguyen Phuong Anh2, 왕명연2, 김상윤2, 신은우2
소속 1Univ. of Ulsan, 2Univ. of ulsan
키워드 촉매(Catalyst)
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