| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Micellization confirmation depend on temperature of poly(ethylene oxide) -b- poly(NiPAM)s using fluorescein dye |
| 초록 |
We have successfully synthesized water-soluble block copolymers exhibiting temperature-responsive phase transition using poly(ethylene oxide)-based macroinitiator via RAFT radical polymerization. The PEO-based macroinitiator was successfully converted into the RAFT (reversible addition fragmentation chain transfer) agent containing the dithioester group. Using the RAFT agent and AIBN as an initiator, RAFT polymerization of N-isopropylacrylamide (NiPAM) was successfully performed in toluene at 80℃ for 8h. Using flourescein dye us having quantum efficiency even in low concentration, confirmed micellization of the temperature - sensitive block copolymer. |
| 저자 |
전희정1, 김정안2, 고다현2, 최송이3, 김경민2
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| 소속 |
1경희대, 2경희대 화학과, 3경희대화학과 |
| 키워드 |
Micellization; flourescein
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| E-Mail |
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