화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 기능성 고분자
제목 Controlling Graphene Defects Using Polyvinylacohol through Hydrogen Bonding
초록 Lately, displays using organic materials such as OLED have been developed due to increase of interest about thinner displays. However, because conjugated organic materials used in displays are easily decomposed by oxygen and water gas, a lot of gas barrier research have been studied to overcome this limitation. Graphene might be one of the best candidates as a gas barrier because an atomically perfect chemical strucutre of graphene does not allow any gases to pass through graphene. However, graphene synthesized through a chemical vapor deposition (CVD) method contains many defects of nano- and micro-meter scales in reality. To solve this problem, we applied polyvinylacohol (PVA) which could make hydrogen bonding with functioal groups in graphene defects. AFM study reveals that PVA could selectively fill holes with micrometer size in graphene by using hydrogen bonding between PVA and functional groups such as carboxylic or hydroxide groups existing at graphene defects.
저자 김윤정1, 강영종2, 안석훈3
소속 1KIST, 2한양대, 3한국과학기술(연)
키워드 graphene defect; gas barrier; polyvinylalcohol
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