화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2021년 봄 (04/21 ~ 04/23, 부산 BEXCO)
권호 27권 1호, p.535
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제목 Low-temperature thermochemical CO2/H2O splitting on transition metal-based oxygen carriers in chemical looping processes
초록 This talk addresses the low temperature thermochemical CO2/H2O splitting to CO/H2 by adopting the concept of chemical looping process. In a typical thermochemical CO2/H2O splitting reaction, the reduced oxides are utilized as oxygen carriers to reduce reactants into CO/H2O. The oxidized oxygen carriers are then thermally reduced subsequently for another splitting progress. However, since this thermal reduction process requires a high operation temperature over 1000 °C, the arrays of stable material selection are extremely limited and operation cost makes it hinder for application. Hence, this talk suggests a way to lower the operation temperature of thermochemical splitting reaction by utilizing reactant gases such as CH4 and H2 for reducing oxygen carriers. The reactant of CO2/H2O can be effectively converted into CO/H2 on the reduced oxygen carrier even at 500-850°C.
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