화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션)
권호 20권 1호
발표분야 (여성인재육성)행동하는 여성-“에너지, 환경, 소재”-여성이 하면 “확” 다르다
제목 Microencapsulation of renewable diol–diisocyanate for self-healing coatings
초록 Polyurethane microcapsules containing healing material (PU) as a core material for self-healing protection coatings were successfully prepared by interfacial polymerization of diol–diisocyanate prepolymer and 1,4-butanediol as a chain extender in an emulsion solution. Microcapsules were observed with an average diameter of 39–72 mm and average shell thickness of 3.8–5.5 mm, while controlling agitation rates (2000–8000 rpm). The PU shell thickness was linearly proportional to the measured capsule diameter with the ratio of capsule shell thickness of -0.08. The core content and synthetic yield were approximately 44–59 wt% and 31–67%, respectively. The self-healing coating systems showed that the ability to recover from damage on the substrate, depending on the diameter and the concentration of the PU capsules in the paint layer, which could control the efficiency.
저자 고은주, 이용택
소속 경희대
키워드 microencapsulation; renewable diol–diisocyanate; self-healing system
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