화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 나노플라즈모닉스 기술 및 응용
제목 Silver layer assisted surface plasmon polariton Raman miscroscopy
초록 We report surface plasmon polariton (SPP) mediated Raman microscopy on dielectric films in contact with a Ag layer at 785 nm with spatial resolution approaching the optical diffraction limit. The excitation and scattered photons couple to the SPP of the Ag film through a hemispherical ZnSe solid immersion lens (SIL). We use the prototypical organic solar cell system of a 1:1 blend of P3HT and PCBM to demonstrate the new microscopy. Calculations of the electric field intensity at the metal–dielectric interface are presented that yield insight into the optimal angular coupling into the Ag SPP and the optimal Ag film thickness. SPP Raman spectra of pure P3HT films are reported for a series of samples with Ag films of varying thickness, confirming excitation via the SPP. SPP Raman images of thermally annealed blend films are presented and compared to conventional confocal Raman images.
저자 유해욱1, Lee J. Richter2, Chris A. Michaels2, 정희태1
소속 1KAIST, 2NIST
키워드 surface plasmon polariton; Raman microscopy; P3HT; silver layer
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