| 학회 | 한국화학공학회 |
| 학술대회 | 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔) |
| 권호 | 12권 1호, p.1139 |
| 발표분야 | 촉매 및 반응공학 |
| 제목 | Synthesis of Cyclic Carbonate from Epichlorohydrin and CO2 using Ionic Liquid as Catalyst |
| 초록 | This study is related to the synthesis of cyclic carbonate from epichlorohydrin and carbon dioxide without using any solvent in the presence of ionic liquid as catalyst. The reaction was carried out in a batch autoclave reactor. The conversion of epichlorohydrin was affected by the structure of the ionic liquid ; the one with the cation of bulkier alkyl chain length and with more nucleophilic anion showed better reactivity. The conversion of epichlorohydrin increased as the temperature increased from 60℃ to 120℃. It also increased with increasing carbon dioxide pressure probably due to the increase of the absorption of carbon dioxide into the mixture of epichlorohydrin and the ionic liquid. |
| 저자 | 이은하, 박대원, 안지연, Manju M. D., 김경훈 |
| 소속 | 부산대 |
| 키워드 | CO2; ionic liquid; Cyclic carbonate |
| 원문파일 | 초록 보기 |
