| 학회 | 한국화학공학회 |
| 학술대회 | 2019년 봄 (04/24 ~ 04/26, 제주국제컨벤션센터) |
| 권호 | 25권 1호, p.622 |
| 발표분야 | 열역학(Thermodynamics) |
| 제목 | High pressure CO2 solubilities in 1,1,2,2-tetrafluoroethanesulfonate(TFES) anion based ionic liquids : [EMIM][TFES], [BMIM][TFES], [Benzyl][TFES] |
| 초록 | We measured the CO2 solubility in three different [TFES] anion-based ionic liquids: 1-Ethyl-3-methylimidazolium 1,1,2,2-tetrafluoroethanesulfonate, 1-Butyl-3-methylimidazolium 1,1,2,2-tetrafluoroethanesulfonate and 1-Benzyl-3-methylimidazolium 1,1,2,2-tetrafluoroethanesulfonate in the experimental ranges of 0.8–36.8 MPa and 303.2–373.2 K. We determined the CO2 solubility by measuring the bubble-point pressure for a fixed CO2 mole fraction, and the order of intensity for CO2 absorption ability was [BMIM][TFES] ＞ [EMIM][TFES] ＞ [Benzyl][TFES]. The Peng-Robinson equation of state (PR-EoS), the conventional van der Waals one fluid mixing rule, and the modified Lydersen-Joback-Reid method were used to correlate and calculate the experimental data. The overall average absolute deviations of pressure (AAD-P) were 1.81, 3.61, and 2.78 % for CO2 + [EMIM][TFES], CO2 + [BMIM][TFES], and CO2 + [Bezyl][TFES] systems, respectively. |
| 저자 | 박광우, 임종성 |
| 소속 | 서강대 |
| 키워드 | 열역학; 상평형 |
| 원문파일 | 초록 보기 |
