화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스))
권호 8권 2호
발표분야 화학공정
제목 Complexation of cerium(III) and neodymium(III) with acetohydroxamic acid in aqueous solution; spectrophotometric determination of stability constants
초록 Acetohydroxamic acid has been studied by absorbance spectroscopy as a complex forming reagent for the trivalent lanthanides(Ce(III) and Nd(III)) in aqueous solution at 1.0 M (NaClO4) ionic strength. Computation relating to the determination of stability constants was performed by regression analysis of UV/VIS spectra using SQUAD program. The stability constants for acetohydroxamic acid with Ce(III) and Nd(III) were obtained with the aid of program SQUAD. The stability constants of Ce(III) and Nd(III) complexes by SQUAD were logβ1=5.05, logβ2=10.60 and logβ3=16.23 for Ce(III), and logβ1=5.90, logβ2=12.22, and logβ3=18.58 for Nd(III).
저자 정동용, 이일희
소속 한국원자력(연)
키워드 Complexation; cerium; neodymium; acetohydroxamic acid; spectrophotometric determination
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