| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
The Reduction of Nitrobenzene Derivatives Using a New Polymer Reagent |
| 초록 |
New N-substituted acrylamide monomer was polymerized with styrene by a suspension polymerization in the presence of crosslinking agent to obtain microporous crosslinked copolymer particles. They were used as a polymer reagent for organic reduction reaction: nitrobenzene and its derivatives were reduced in high yield by using a Zn/NH4Cl system in water in the presence of the prepared copolymer particles without any organic solvent at mild condition. Unlike a conventional reduction utilizing the Zn/NH4Cl system, as an example, the use of the microporous copolymer reagents enables the high selectivity of nitrobenzene to hydrazobenzene during the reduction. |
| 저자 |
이상미, 조진, 한양규
|
| 소속 |
한양대 |
| 키워드 |
nitrobenzene reduction; new polymer reagent; high selectivity
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| E-Mail |
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