| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO)) |
| 권호 |
21권 2호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
CF4 degradation to ethanol by electrochemically generated Cu1+[Ni2+(CN)4]1- at electro-scrubbing |
| 초록 |
CF4 degradation by using commercially available technologies ended up with another kind of greenhouse gas and corrosive side products. This investigation aimed to develop CF4 removal at room temperature with formation of useful product ethanol by attempting an electrogenerated Cu1+[Ni2+(CN)4]1- mediator. In the initial electrolysis of bimetallic complex at anodized Ti cathode demonstrated the Cu1+[Ni2+(CN)4]1- formation, which was confirmed by additional ESR results. The degradation of CF4 followed mediated electrochemical reduction (MER) by electrogenarted Cu1+[Ni2+(CN)4]1-. The removal efficiency of CF4 was achieved 95% by this present electroscrubbing process at room temperature. Through the spectral results of online and offline FTIR analyzer either in gas or in solution phase demonstrated that the formed product during the removal of CF4 by electrogenerated Cu1+[Ni2+(CN)4]1- at electroscrubbing was ethanol (CH3CH2OH) with small amount of trifluoroethane (CF3CH3) intermediate. |
| 저자 |
A.G.Ramu, G.MUTHURAMAN, 문일식
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| 소속 |
순천대 |
| 키워드 |
Bimetallic mediator; Cu1+[Ni2+(CN)4]1-; MER; CF4 degradation; Ethanol formation
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| E-Mail |
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