| 학회 |
한국화학공학회 |
| 학술대회 |
2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터) |
| 권호 |
16권 2호, p.2206 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Preparationof Ru-based Catalysts forHydrogenolysis of Glycerol to 1,2-Propanediol. |
| 초록 |
Recently, the production of glycerol has been increased with the production of biodiesel as a clean fuel. One of the most attractive approaches of converting glycerol is to produce propanediol(PDO) by selective hydrogenolysis of glycerol. In this works, the Ru-based catalysts were prepared by co-precipitation and/or impregnation methods in order to improve 1,2-PDO selectivity. The prepared catalysts were characterized by N2 physisorption, CO chemisorption, XRD, SEM, TPR and TPD techniques. The catalytic hydrogenation of glycerol to 1,2-PDO over the Ru-based catalysts was investigated at 453 K, 25 bar of initial H2 pressure and 20 wt% glycerol aqueous solution for 18 h. It was found that the Ru base hydrotalcite catalyst showed high activity with glycerol conversion of 50 % and 1.2-PDO selectivity of 85 %.It was found that the selectivity of 1,2-PDO was increased with increasing the acidity of catalyst. |
| 저자 |
이승환, 박문주, 정재선, 민동원, 강정식, 문동주
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| 소속 |
한국과학기술(연) |
| 키워드 |
Glycerol; Propanediol; Hydrogenolysis; Ru-based catalyst
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| E-Mail |
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| 원문파일 |
초록 보기 |
