화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 생체재료_포스터
제목 Sensitive Detection of Polycyclic Aromatic Hydrocarbons using β-CD Dimer-immobilized Ag Assembly Embedded SiO2 Nanoparticles
초록 We design the sensor materials, which have a β-Cyclodextrin dimer on silver nanoparticles embedded with silica nanoparticles (Ag@SiO2 NPs) structure, and measured their ability of detecting polycyclic aromatic hydrocarbons (PAHs). As a substrate for intensifying surface-enhanced Raman scattering(SERS) signal, Ag@SiO2 NPs were used as sensitive SERS structure and a dimeric β-CD was added on the surface of Ag NPs to capture PAHs. The structure of β-CD dimer@Ag@SiO2 NPs was confirmed by TEM, UV-vis and ATR-FTIR. The β-CD dimer@Ag@SiO2 NPs had a wide linearity range of 10-7 M to 10-2 M with a low detection limit of 10-8 M for detecting perylene (one kind of PAHs). Furthermore, the possibility of the β-CD dimer@Ag@SiO2 NPs was demonstrated as a selective and a multiplex detection for organic materials and various PAHs. This approach of combining an assembled structure and the ligands to recognize target has potential for utilizing in sensitive analytical sensors.
저자 함은일1, 김형모1, Xuan-Hung Pham1, 김태한1, 이윤식2, 전봉현1
소속 1건국대, 2서울대
키워드 Assembled Ag NPs; β-cyclodextrin dimer; PAHs; SERS detection
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