| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO)) |
| 권호 |
23권 1호 |
| 발표분야 |
석유화학·윤활유_포스터 |
| 제목 |
Ordered mesoporous Co3O4-Al2O3 catalysts for CO hydrogenation to hydrocarbons: Effects of phosphorus modifier to an enhanced catalytic activity and stability |
| 초록 |
A gradual increasing demand for alternative clean fuels has made a gas-to-liquids (GTL) process to be one of the promising technologies, where Fischer-Tropsch synthesis (FTS) reaction by CO (or CO2) hydrogenation is a crucial step to convert syngas into synthetic fuels by combining with various reforming processes even for CO2-rich natural (or shale) gases. In present study, the mesoporous Co-based FTS catalyst was investigated to find how to increase the catalytic stability with a proper promoter for FTS reaction. The highly ordered mesoporous Co-Al mixed metal oxide (m-CoAl) revealed a stable catalytic and structural stability with an optimal amount of phosphorus modifier. The hydrophobic SiO2-like tridymite AlPO4 surfaces formed on the matrices of the mesoporous m-CoAl effectively prevented the heavy wax (or coke precursors) depositions. |
| 저자 |
박용민, 배종욱
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| 소속 |
성균관대 |
| 키워드 |
Fischer-Tropsch synthesis (FTS) reaction; Ordered mesoporous Co3O4-AlOx; Structural stability; Phosphorus modifer; Nanocating methods; hard template of KIT-6
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| E-Mail |
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