학회 |
한국화학공학회 |
학술대회 |
2005년 가을 (10/21 ~ 10/22, 인하대학교) |
권호 |
11권 2호, p.1963 |
발표분야 |
분리기술 |
제목 |
Facilitated transport membranes with SPEEK-AgNO3 for the separation of isoprene/n-pentane mixtures |
초록 |
The facilitated transport membranes, sulfonated poly(ether ether)ketone (SPEEK)-AgNO3, were prepared and tested for separation of the isoprene/n-pentane mixtures. The SPEEK-AgNO3 membranes showed good selectivity for isoprene over n-pentane and long-term stability. The degree of sulfonation (DS) of SPEEK was measured by 1H NMR spectroscopy. The performances of the SPEEK-AgNO3 membranes were significantly affected by the degree of sulfonation (DS) of PEEK. The selectivity for isoprene over n-pentane increased with the increasing DS of PEEK. In a liquid-liquid membrane contactor system using a hollow fiber membrane module, it was found that the performance of the membrane was influenced by the concentration and the flow rate of Ag solution used as an absorption solution and the flow rate of isoprene/n-pentane mixtures. |
저자 |
최현우1, 안의섭1, 정병만1, 강석현1, 장성철1, 김동범1, 이창하2, 김훈식3, 최대기1
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소속 |
1한국과학기술(연), 2연세대, 3경희대 |
키워드 |
facilitated transport; olefin/paraffin; isoprene/n-pentane; membranes; separation
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E-Mail |
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원문파일 |
초록 보기 |