| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
| 권호 |
38권 1호 |
| 발표분야 |
고분자가공/복합재료 |
| 제목 |
Rational Design of POSS Fillers for Simultaneous Improvements of Thermomechanical Properties and Lowering Refractive Indices of Polymer Films |
| 초록 |
We present here the design and synthesis of the polyhedral oligomeric silsesquioxane (POSS)-based dual functional molecular fillers for simultaneously lowering refractive indices and improving thermomechanical properties of conventional polymers. We prepared the composite films with poly(methyl methacrylate) and polystyrene containing the series of the POSS derivatives with the single functional unit for interacting with polymer chains and hepta-cyclopentyl substituents for creating exclusive volumes around the POSS core. From the measurements of refractive indices of polymer composites, it was revealed that all POSS fillers can lower the refractive index of the films. In addition, thermal stabilities and mechanical properties were enhanced by adding POSS fillers. The filler effect on the thermal properties can be explained by the structural feature of POSS. |
| 저자 |
전종환 |
| 소속 |
교토대 |
| 키워드 |
POSS; Refractive index; Filler
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| E-Mail |
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