화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 기능성 고분자
제목 Dispersion of the Single-Walled Carbon Nanotubes using poly[2-(dimethylamino)ethyl methacrylate]-co-polystyrene.
초록 Single-walled carbon nanotubes(SWNTs) have been attracting great attention due to their remarkable mechanical and electrical properties with many potential applications. However, SWNTs exist as a bundle due to a strong intertube van der Waals attraction. In order to utilize those properties, efficient dispersion of SWNTs is firstly required. In this study, poly[2-(dimethylamino)ethyl methacrylate]-co-polystyrene(PDMAEMA-co-pSt) was synthesized and used as polymeric dispersants for SWNTs in organic solvent. PDMAEMA-co-pSt with different copolymer composition were prepared by atom transfer radical polymerization(ATRP) and characterized by gel permeation chromatography(GPC) and 1H NMR. With PDMAEMA-co-pSt, SWNTs were effectively dispersed through non-covalent functionalization by ultrasonication in tetrahydrofuran. Unbundled structures of SWNTs were observed by transmission electron microscopy(TEM). Using the turbiscan optical analyzer, dispersion stabilities of SWNTs were compared.
저자 김동현1, 김건우1, 김봉수1, 박상우1, 신권우2, 한종훈2, 백현종1
소속 1부산대, 2전자부품(연)
키워드 carbon nanotube; SWNT; CNT; dispersion; dispersant; ATRP
E-Mail