| 학회 |
한국고분자학회 |
| 학술대회 |
2003년 가을 (10/10 ~ 10/11, 부경대학교) |
| 권호 |
28권 2호, p.384 |
| 발표분야 |
의료용 고분자 부문위원회 |
| 제목 |
Formation of Unimolecular Micelle of Multiblock/Graft Copolymers: Brownian Dynamics Simulation Approach |
| 초록 |
Brownian dynamics simulation is conducted to investigate the effect of polymer architecture on the formation and structure of unimolecular micelle. Multiblock copolymer and graft copolymer are constructed using bead-spring model and Lennard-Jones interactions are employed to give amphiphilic nature for each block. Formation of flower-like and flower-connecting-type unimolecular micelle through intramolecular association is observed for multiblock and graft copolymers below critical aggregation temperature. It is also observed that the size of flower-like micelle is strongly affected by the number of repeating units. Various micellar properties such as critical aggregation temperature, average aggregation number, and the structure of flower-like micelle are obtained and compared with theoretical prediction.
|
| 저자 |
김광희, 허준, 조원호
|
| 소속 |
서울대 |
| 키워드 |
Unimolecular micelle; multiblock copolymer; graft copolymer; comb copolymer
|
| E-Mail |
|
