| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
20권 2호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Electrochemical study on the redox behavior of mediator in 1-Butyl-3methyl imidazolium Trifluoromethane sulfonate Ionic liquid in water mixture |
| 초록 |
Room temperature ionic liquid is said to be a green solvent for the synthesis of organic compounds, most of the reported works were based on the potentiostatic electrolysis in ionic liquid. But galvanostatic electrolysis in RTIL is not easy as aqueous electrolytes because of decomposition of ionic liquid species due to over voltage and addition of organic solvents tends to reduce the cell potential but it has limited to some extent. Based on the idea, we have performed the galvanostatic electrolysis of 1-Butyl-3methyl imidazolium Trifluoromethane sulfonate (BMIMCF3SO3) Ionic liquid in presence of water and mediators. Both systems were observed that suppressed the cell potential and 2M BMIMCF3SO3 showed the optimum condition for the electrolysis in divided Cell. The redox behavior of mediators in BMIMCF3SO3 + H2O mixture were analyzed by potentiometric titration with aqueous H2O2 solution. |
| 저자 |
G. MUTHURAMAN, K.Kannan, 문일식
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| 소속 |
순천대 |
| 키워드 |
Ionic liquid water mixture; Galvanostatic electrolysis; mediators; potentiometric titration.
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| E-Mail |
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