화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 기능성고분자-막분리용 고분자
제목 Synthesis and Characterization of Sulfonated Poly (arylene ether sulfone) Multiblock Copolymers containing DHTPE and BFTPB for PEMFC
초록 Poly (arylene ether sulfone) Multiblock Copolymers containing DHTPE and BFTPB were synthesized via a coupling reaction between phenoxide-terminated hydrophilic oligomers(DHTPE and BFTPB) and fluorophenyl end-capped hydrophobic oligomers(BPS and FPS). The block length and block combination of copolymers were varied by precisely controlling the molecular weight Mn and end group functionality of oligomers. The resulting hydrophilic-hydrophobic sequenced multiblock copolymers afforded transparent, ductile, and tough membranes by solution casting from DMAc. Membrane properties of these copolymers were characterized including intrinsic viscosity, thermal stabilities, morphology, water uptake, and proton conductivity.
저자 임영돈, 서동완, 이순호, 모니룰, 이현철, 김환기
소속 건국대
키워드 PEMFC; block copolymer; poly(ether sulfone)s; sulfonation
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