| 학회 |
한국공업화학회 |
| 학술대회 |
2013년 봄 (05/01 ~ 05/03, ICC JEJU) |
| 권호 |
17권 1호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Synthesis and thermal properties of 3-ethyl-3-(ferrocenylmethoxymethyl) oxetane and oxetane derivative by cationic ring-opening copolymerization |
| 초록 |
The compound 3-ethyl-3-(ferrocenylmethoxymethyl) oxetane (FMEO) was used as a co-monomer for ring-opening polymerization, and poly (3-ethyl-3-(ferrocenylmethoxymethyl) oxetane-co-oxetane) (poly (FMEO-co-OXE)) and poly (3-ethyl-3-(ferrocenylmethoxymethyl) oxetane-co-3-ethyl-3-[(2-ethylhexyloxy)methyl]oxetane) (poly (FMEO-co-EHOX)) were synthesized by cationic ring-opening copolymerization in the presence of BF3-etherate and diethyleneglycol as an initiator system. The structural analysis of all products was performed using Fourier transform infrared (FT-IR) spectroscopy and nuclear magnetic resonance (NMR). The thermal behaviors of the poly (FMEO-co-OXE) and poly (FMEO-co-EHOX) were compared using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). |
| 저자 |
조봉상, 김정수, 권정옥, 노시태
|
| 소속 |
한양대 |
| 키워드 |
ferrocene; cationic ring opening polymerization; thermal properties; propellants
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| E-Mail |
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