| 학회 | 한국화학공학회 |
| 학술대회 | 2002년 봄 (04/26 ~ 04/27, 강원대학교) |
| 권호 | 8권 1호, p.921 |
| 발표분야 | 열역학 |
| 제목 | 마이크론 사이즈 젤 입자의의 상거동 |
| 초록 | Temperature and ionic strength sensitive hydrogels play an important role in the application of pharmacy, medicine and separation operations in biotechnology. The most important thermodynamic property of gel is the degree of swelling for application. Thermodynamically, swelling behaviors of nonionic hydrogels were interpreted by the polymer-solvent mixing free energy and elastic free energy. In this study, to successful prediction of nonionic hydrogels, we combined the Modified Perturbed Hard Sphere Model (MPHSC) and Flory and Erman‘s theory of elasticity. We used Modified PHSC developed by Chapman’s bonding term as the reference term and van der Waals attractive term as the perturbation. Our proposed model shows good agreements with experimental PVT data water and gel swelling data. |
| 저자 | 홍영표, 배영찬 |
| 소속 | 한양대 |
| 키워드 | equation of state; attractive term; PHSC |
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| 원문파일 | 초록 보기 |
