| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Novel cyclic sulfonium iodide containing siloxane high performance electrolyte for dye-sensitized solar cell |
| 초록 |
A new type of solid and gel-state ionics based on siloxane cyclic sulfonium iodides was synthesized and used as electrolytes in dye-sensitized solar cells. The siloxane bis-cyclic sulfonium iodides (SiCSI1, 2) are shown light yellow with solid state, but siloxane mono- cyclic sulfonium iodide (SiCSI3) is brown color with gel state. The resulting electrolytes were characterized by 1H NMR, FT-IR, TGA and diffusion coefficient. The thermo oxidative stabilities of the prepared ones are lower than that of DMII because the bond strength of S+-C in thiophenium is lower than that of N+-C in imidazolium. Among the three SiCSIs based electrolytes, SiCSI3 showed a maximum photo-conversion efficiency of 7.3%. In addition, the performance of the DSSCs showed relatively reasonable compared with the imidazolium type DMII electrolyte. |
| 저자 |
이순호, 전영태, 이상영, 임영돈, 이현철, 김환기
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| 소속 |
건국대 |
| 키워드 |
염료감응형 태양전지; 전해질; DSSC; electrolyte
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| E-Mail |
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