화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 고분자가공/복합재료
제목 Thermal diffusivity of polyamide/graphite composites
초록 The thermal diffusivity (TD) of graphite intercalated compound (GIC)/polyamides (PA6, PA66 and PA12) and graphite/PA composites were investigated. Composites were prepared by an in-situ exfoliation melting process and thermal diffusivity of the composites was measured by a laser flash method. The surface chemistry of the GIC and graphite was investigated using FTIR and the fracture morphology of the composites was observed by FE-SEM. Crystallinity and melting point of the composites measured by DSC. TD of the in-situ exfoliation processed PA/GIC composites showed a significant improvement over that of conventional PA/graphite composites. We suggest that the larger flake size and high expansion ratio of the GIC during the in-situ exfoliation process provided thermal diffusivity enhancement as well as 18 times at 20vol% of GIC. Melting point and crystallinity of the composites decreased with addition of the graphitic filler while the GICs provided higher crystallinity graphite ones.
저자 Mohammad Poostforush1, 김유란1, 고현웅1, 이성구2, 김성룡1
소속 1충주대, 2한국화학(연)
키워드 Thermal diffusivity; Polyamide; composites; in-situ exfoliation
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