화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 분자전자 부문위원회 I
제목 Tailoring Chemical and Morphological Properties of Graphene Oxide via γ-ray Irradiation for Enhanced Efficiency of Perovskite Solar Cells
초록 In this study, we demonstrate that surface chemistry of graphene oxide (GO) is effectively tailored by γ-ray irradiation, and the tailored properties of GO can contribute to the enhancement of the performance of perovskite solar cells. Aqueous GO was exposed to high energy 60Co γ-ray, which resulted in oxidation of GO: The reaction induced by γ-ray irradiation increased the oxygen content of the GO and scattered large GO agglomerates into GO sheets with small lateral dimensions, which leads to uniform distribution in PEDOT:PSS layer. In addition, PEDOT:PSS layer with γ-GO exhibited higher hydrophobicity than the pristine PEDOT:PSS layer, which facilitated the uniform grain growth of perovskite. As a result, GO with tailored chemical and morphological properties significantly improved the hole transport properties in perovskite solar cells.
저자 조재상1, 장웅식1, 이민지1, 문성식2, 박종혁3, 왕동환1
소속 1중앙대, 2Univ. of Minnesota, 3연세대
키워드 γ-ray; Graphene; Perovskite; Photovoltaics; PEDOT:PSS
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