| 초록 |
Liquid Phase solvent free catalytic oxidation of Toluene was investigated over transition metal doped Mesoporous Carbon nitride using O2 as a terminal oxidant. A series of metal-doped graphitic carbon nitride catalyst (Co-, Fe-, Mn-, (Co/Mn)-, and Ni-UF-MCN) were successfully synthesized by wet incipient impregnation method. It was found that the Fe (III)-doped graphitic UF-MCN catalyst was the most efficient catalytic system and exhibited a highest conversion of 6% with selectivity’s of (45%) Benzaldehyde and (45%) Benzoic acid. The Co-Presence of CO2 under analogous conditions showed enhancement in conversions (12%) and elevated selectivity’s (87%) towards Benzoic acid with minor product as Benzaldehyde. |
