화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2005년 봄 (04/14 ~ 04/15, 전경련회관)
권호 30권 1호, p.593
발표분야 복합재료
제목 Preparation and properties of covalently bonded polypropylene/layered silicate nanocomposites using the modification of clay
초록 Polymer/clay nanocomposites were widely used in various applications because they showed substantial enhancements of thermal and mechanical properties compared to conventional filler composites.1 In this work, we studied polypropylene/clay nanocomposites by modified clay with amino silanes2 to introduce new chemical bonds between clay and MAPP. We prepared polypropylene/clay nanocomosites with the polypropylene, modified clay and MAPP through the melt-compounding method. We observed the exfoliated structure of silicate layers in the PP matrix from X-ray diffraction (XRD) and transmission electron microscopy (TEM). The thermal and mechanical properties of nanocomposites were found to improve substantially over those of the existing nanocomposites.





fig. 1. Thermogravimetric analysis of PP and PP/clay nanocomposites







Reference
1. T. J. Pinnavaia and G.W Beall, Polymer-Clay Nanocomposites, John Wiley & Sons, Ltd, 2002.
2. C. M. Leu, Z. W. Wu, and K. H. Wei, Chem. Mater, 14, 3016 (2002).
저자 배진우1, 이용범1, 홍채환1, 이춘수2, 남병욱3, 조재영1
소속 1서울대, 2현대자동차, 3한국기술교육대
키워드 nanocomposites; polypropylene; clay; modification; amino silane
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