화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.1463
발표분야 분리기술 (Separation Technology)
제목 Efficient CO2/N2 Separation of MOF-LDH/XLPEO Membranes
초록 Metal-organic frameworks (MOFs) are emerging porous materials used for CO2 separation because of its high surface area and tunable structure. Recently, several research works have been conducted to fabricate polymer composites containing MOFs as fillers to make mixed matrix membranes (MMMs). Herein, MMMs incorporating ZnCr-LDH/NH2-MIL-125(Ti) as filler particles in cross-linked polyethylene oxide (XLPEO) polymer were fabricated. Different loading amounts of filler ranging from 0 to 10 wt % were used in XLPEO. The membranes were characterized by SEM, EDX and XRD analysis. Gas separation properties of these MMMs were investigated and compared with the original XLPEO membrane. The results indicate that the ZnCr-LDH/NH2-MIL-125(Ti) acted as efficient fillers in the matrix and increased the CO2 permeance as well as CO2/N2 selectivity. This improved performance is attributed to the homogeneous dispersion of filler particles in the XLPEO matrix. This work provides useful insight for the efficient separation of CO2 from flue gases by MMMs. Details of the work will be presented.
저자 Shah Syed Fawad Ali1, Sohail Muhammad1, 김태우2, 김현욱2
소속 1Korea Institute of Energy Research, 2한국에너지기술(연)
키워드 CO2 분리; 막분리
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