화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 에너지저장변환_포스터
제목 Improvement in stability and performance of polymer solar cells by modifying PEDOT:PSS hole extraction layer with conjugated polymer electrolyte
초록 In this study, we fabricated normal structured polymer solar cells (PSCs) by introducing a hole extraction layer (HEL) that consisted of poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) and conjugated polymer electrolyte (CPE). The CPE can act as a conjugate base against the PSS and screen the coulombic attraction between PEDOT chains and PSS chains. By blending PEDOT:PSS and CPE, the acidity of the HEL solution and stability of the surface morphology and potential of the HEL film in air were reduced. The changes of surface properties were analyzed by using atomic force microscopy (AFM) and electrostatic force microscopy (EFM). As a result, the half-life of the PSC fabricated with blended HEL was five times better at ambient condition (25 ℃ and 40% humidity) without encapsulation as compared to the pristine PEDOT:PSS-based device.
저자 이의진, 정승은, 최민희, 문두경
소속 건국대
키워드 polymer solar cells; stability; hole extraction layer; conjugated polymer electrolytes
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