| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Shape Control for Aggregation Studies -Indoline Chromophores |
| 초록 |
Conjugated organic push-pull compounds typically have high dipole moments and as a consequence tend to aggregate with each other, which in turn can diminish their NLO response. Consequently there is a need to make structural modifications to many basic chromophores that are designed to: (i) minimize aggregation between the chromophores (ii) improve their solubility in non-polar solvents and (iii) increase their NLO figure of merit. We have made such structural modifications to a suite of zwitterionic chromophores, including shape control of the π-conjugated system (prolate to oblate) via the incorporation of bulky substituents. UV-vis spectroscopic data and X-ray structural data has been obtained for the compounds will be used to support the validity of the proposed strategy. |
| 저자 |
M.Delower H.Bhuiyan1, Anderw J2, Kay1, Graeme J.Gainsford2
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| 소속 |
1Industrial Research Limited, 2New Zealand |
| 키워드 |
chromophore; indoline; conjugate; NLO
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| E-Mail |
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