화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 고분자 가공/복합재료
제목 Electrical Properties of Silicone Composites Filled with Silicone oil Modified Multi-Walled Carbon Nanotubes Decorated Silver Nanoparticles
초록 The purpose of experimental is to confirm the electrical properties of silicone composites filled with silicone oil modified multi-walled carbon nanotubes (MWNTs) decorated silver nanoparticles prepared by solution processing. The pristine MWNTs are oxidized (COOH-MWNTs) and converted to the acyl chloride functionalized MWNTs (COCl-MWNTs) using thionyl chloride to introducing silicone oil. Fourier transform infrared spectrometer (FTIR) and thermogravimetric analyzer (TGA) results show that COOH-MWNTs are converted to COCl-MWNTs, which are subsequently reacted with silicone oil (Si-MWNTs). After, Si-MWNTs are decorated with silver nanoparticles. The difference of morphology of COOH-MWNTs, Si-MWNTs and Si-MWNTs decorated silver nanoparticles is observed by high resolution transmission electron microscopy (HRTEM). Silicone/Si-MWNTs decorated silver nanoparticles composites are shown lower percolation threshold than common silicone composites.
저자 이광세, 윤호규
소속 고려대
키워드 Modification; Silicone oil; Silver; MWNTs; Conductivity
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