학회 |
한국공업화학회 |
학술대회 |
2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center)) |
권호 |
21권 1호 |
발표분야 |
환경에너지 |
제목 |
Novel Non-Metal Cathode Catalyst for Oxygen Reduction Reaction in Microbial Fuel Cells |
초록 |
The nitrogen and phosphorus-doped ordered mesoporous carbon (NPOMC) with highly active non-metal oxygen reduction catalyst was synthesized and showed comparable oxygen reduction reaction (ORR) activity to conventional cathode catalyst such as platinum. In this study, we reported performance of NPOMC in MFC and electrochemical properties with using LSV, CV and EIS as compared to platinum with platinum impregnated carbon black (Pt/C) catalysts in air-cathode MFC. In addition, we compared with effect of cathode electrode surface by microbe for NPOMC ORR mechanism between both MFCs. The synthesized NPOMC achieved a remarkable on-set potential compared to the previously reported metal-free catalysis in MFC. The open circuit potential and power density using NPOMC as compared to Pt/C, were 0.43 V and 0.58V, 245.77 mW/m2 and 329.78 mW/m2, respectively. The NPOMC showed a comparable voltage and maximum power density (75%) with considering the cost of just 10% of the platinum catalyst. |
저자 |
송영은1, 이승현2, 김창만1, 전병훈3, 이진우2, 김중래1
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소속 |
1부산대, 2포항공대, 3한양대 |
키워드 |
Microbial fuel cell; non-metal catalyst; porous structure; oxygen reduction reaction (ORR)
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E-Mail |
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