화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 기능성 고분자
제목 Influence of Crosslink on the Transport Properties of Proton Exchange Membranes
초록 Highly sulfonated-fluorinated poly(arylene ether) was synthesized via nucleophilic aromatic substitution. The synthesized polymer with alternatively hydrophilic and hydrophobic component in repeating unit of the polymer possessed high molecular weights and good film-forming capability for transparent and flexible membranes. The polymer exhibited excellent oxidative and dimensional stability due to the highly fluorinated aromatic main chain. Thermal properties of the polymer membranes were characterized by DSC and TGA. The proton conductivity, water uptake and swelling ratio of membranes was observed as changing the crosslinking time.
저자 이관수, 정명환, 이재석
소속 광주과학기술원
키워드 fluoropolymer; poly(arylene ether); fuel cell; proton exchange membrane; proton conductivity; sulfonated polymer
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