| 학회 |
한국공업화학회 |
| 학술대회 |
2005년 가을 (10/28 ~ 10/29, 건국대학교) |
| 권호 |
9권 2호 |
| 발표분야 |
촉매 |
| 제목 |
CO oxidation over Fe oxide-promoted Pt/γ-Al2O3 |
| 초록 |
Selective CO oxidation in the presence of excess hydrogen and complete CO oxidation was studied over Fe oxide-promoted Pt/γ-Al2O3 catalyst. Various factors in the preparation of catalysts such as the molar ratio of Fe/Pt, the sequence of impregnation, calcinations temperatures and reduction temperatures were examined. XRD, CO chemisorption, TPR, TPO, and XANES were conducted to characterize active catalysts. The catalytic activity for CO oxidation was enhanced at low temperatures over Fe oxide-promoted Pt/γ-Al2O3 catalyst compared with Pt/γ-Al2O3 catalyst. The positive effect of water vapor on CO oxidation was also observed. The gradual decrease in the catalytic activity was observed at low temperatures, which is caused by the partial oxidation of Fe oxide. |
| 저자 |
박은덕1, 고은용1, 서경원1, 이현철2, 김순호2, 이두환2
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| 소속 |
1아주대, 2삼성종합기술원 |
| 키워드 |
CO oxidation; PROX; Pt; Fe
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| E-Mail |
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