화학공학소재연구정보센터
학회 한국재료학회
학술대회 2010년 봄 (05/13 ~ 05/14, 삼척 팰리스 호텔)
권호 16권 1호
발표분야 C. Energy and the Environment(에너지 및 환경재료)
제목 Hydrogen-induced embrittlement in hydrogen separable Ni-Al metallic membrane
초록 Metallic glasses showing various functions have been newly at the center of attention in the field of hydrogen separable membrane. The main reason of this interest is due to the comparatively high permeability and resistance to hydrogen embrittlement of hydrogen separable amorphous membrane. Despite extensive study, the mechanism of hydrogen permeation and embrittlement have remained unclear. Therefore, in order to investigate the structural effect in amorphous membrane on the diffusivity of hydrogen and resistance to hydrogen embrittlement, we varied the atomic packing structure of Ni-Al amorphous membrane by changing cooling rate and examined its effect on two permeation properties. Finally, using Voronoi tessellation method, we analyzed the short-range ordering (SRO) structure of the simulated alloys and structural change by hydrogen charging which is related to the hydrogen embrittlement mechanism. We expect that this study in terms of structure could suggest the methodology to design hydrogen separable membrane of good quality, which can replace currently used high cost Pd-based membrane.
저자 박경원1, Shibutani Yoji2, Fleury Eric1
소속 1한국과학기술(연), 2오사카 대
키워드 metallic glasses; hydrogen; embrittlement; permeation
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