| 학회 |
한국화학공학회 |
| 학술대회 |
2019년 봄 (04/24 ~ 04/26, 제주국제컨벤션센터) |
| 권호 |
25권 1호, p.1029 |
| 발표분야 |
촉매 및 반응공학(Catalysis and Reaction Engineering) |
| 제목 |
Production of high calorific synthetic natural gas using cobalt supported-catalysts |
| 초록 |
Synthetic natural gas (SNG) from coal gasification is an environmentally friendly energy source. However, its heating value is lower than the standard heating value for power generation (especially in South Korea and Japan). This problem could be solved by adding C2-C4 hydrocarbons through Fischer-Tropsch reaction. In this study, Catalytic performance and characterization were investigated to elucidate effect of metal support interaction between cobalt and support (Al2O3 and SiO2). The TPR profile of the Co/SiO2 showed the lower reduction temperature than that of the Co/Al2O3. The XRD peaks of Co/SiO2 showed Co metal peak from Co3O4 after reduction at 400 °C, while Co/Al2O3 did not indicate Co metal peak but CoO peak. The Co/SiO2 exhibited higher CO conversion compared to Co/Al2O3 under H2/CO = 3.1, 10 bar and 300 °C, because of better reducibility of cobalt in Co/SiO2. In addition, its heating value is similar to that of noble metal catalyst in previous literature. Therefore, Co/SiO2 could be the promising catalyst for the production of high calorific SNG. |
| 저자 |
김태영1, 조성빈1, 이철호1, 채호진1, 강석환2, 김준우3, 이종민4, 이수출1, 김재창1
|
| 소속 |
1경북대, 2고등기술(연), 3포항산업과학(연), 4씨이에스 |
| 키워드 |
촉매 |
| E-Mail |
|
| 원문파일 |
초록 보기 |
