화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 봄 (04/12 ~ 04/13, 제주 ICC)
권호 32권 1호
발표분야 기능성 고분자 캡슐 공정 및 소재
제목 Electrofluorescent modulation of Anthracene oligomer/cooligomer using TBAI/I2 dopant
초록 Anthracene oligomer and anthracene/EDOT cooligomer were synthesized from Friedel-Craft’s induced polymerization. Herein, we studied the electrofluorescent modulation property of Anthracene oligomer/cooligomer using TBAI/I2 dopant. Adding the tetrabutylammounium iodide(TBAI)/iodine(I2), anthracene oligomer/cooligomer could be form charge transfer complex. In solution state, effect of TBAI/I2 dopant could show remarkable dynamic fluorescence quenching. Additionally, we present the solid device containing viscous polymer electrolyte having TBAI/I2 and anthracene oligomer/cooligomer mixture. The fluorescent device was reversible electrochemically switched on and off as a function of the applied potential. The results are meaningful for fluorescence switching sensor reserch. These method can improve the optical and electrochemical performance in aromatic polymer luminescent field.
저자 권태창, Krishnamurthy Rameshbabu, 김은경
소속 연세대
키워드 anthracene; EDOT; electrofluorescent; switching
E-Mail