화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔)
권호 12권 1호, p.328
발표분야 분리기술
제목 Gas permeation properties of the carbon membranes derived from the polymer blend of poly(phenylene oxide)(PPO) and a thermolabile polymer
초록 The selection of a polymeric precursor is one of the most important considerations since it can yield a series of membranes having micropores of desired molecular dimensions through the pyrolysis at a desired temperature. The carbon membranes derived PPO/PVP precursors were prepared using a polymer blend of the thermally stable and labile polymer in order to investigate influence of the PVP molecular weight on the gas permeation performance. The permeation results showed that the permeances especially for the gas species with larger molecular size increased due to increased membrane pore structure and the enhanced diffusional pathway for the gas transport through carbon membranes. It is considered that the addition of the thermally labile polymer can control the pore structure in the carbon membrane derived from the PPO/PVP with different PVP molecular weight.
저자 이홍주1, Hiroyuki Suda2, Kenji Haraya3, 김동표2
소속 1충남대, 2National Institute of Advanced Industrial Science and Technoloy (AIST), 3Japan
키워드 Carbon membrane; gas separation; polymer blend
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