화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 봄 (05/01 ~ 05/03, ICC JEJU)
권호 17권 1호
발표분야 포스터-나노
제목 Silver Nanocomposite Membranes Containing Activated Silver NanoparticlesDispersed in a Polymer Blend Matrix of PEBAX and Poly(vinylpyrrolidone) for Facilitated Olefin Transport.
초록 It has been known that the facilitated olefin transport membrane containing carriers interacting reversibly and specifically with olefin results in high separation performance of olefin/paraffin mixtures. Herein, membranes containing silver nanoparticles (Ag NPs) as olefin carriers dispersed in blends of two polymers; polyvinylpyrrolidone (PVP) and poly(amide-b-ether) (PEBAX2533) were prepared. PVP is a well-known polymer acting as a capping agent to stabilize nano-sized and uniformly dispersed Ag NPs. However PVP is very brittle and low permeable to gas. Therefore we added PEBAX into PVP to improve its film property and gas permeability. Consequently, the permeance and the film forming property were improved to a large extent at the expense of the selectivity.
저자 최형우, 이정현, 김영래, 강용수
소속 한양대
키워드 PEBAX; PVP; silver nanoparticles; facilitated olefin transport
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