학회 |
한국고분자학회 |
학술대회 |
2017년 봄 (04/05 ~ 04/07, 대전컨벤션센터) |
권호 |
42권 1호 |
발표분야 |
분자전자 부문위원회 I |
제목 |
Synergetic Evolution of DPP-Based Polymeric Semiconductor for High Reproducibility and Performance |
초록 |
A new random copolymer consisting of similarly shaped D-A building blocks of DPP-SVS and DPP-TVT is designed and synthesized. The resulting P-DPP-SVS(5)-TVT(5) with an equal molecular ratio of the two building blocks produced significantly enhanced solubility when compared to that of the two homopolymers, PDPP-SVS and PDPP-TVT. This unique property produces a high charge carrier mobility of 1.23 cm2V−1s−1 of PDPP-SVS(5)-TVT(5), as determined from organic thin film transistor (OTFT) measurements. The high solubility of PDPP-SVS(5)-TVT(5) promotes formulation of high-viscosity solutions which could be successfully processed to fabricate large-areal OTFTs onto hydrophobically treated 4 in. wafers. This result shows that producing devices with extremely narrow distribution of OTFT parameters. This is the first study to report on successfully realizing large-areal reproducibility of high-mobility polymeric semiconductors. |
저자 |
김유헌1, 조장환2, 박성종1, 권순기1, 정대성2, 김윤희1
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소속 |
1경상대, 2중앙대 |
키워드 |
OTFT; D-A Random Copolymer
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E-Mail |
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