| 학회 | 한국고분자학회 |
| 학술대회 | 2005년 봄 (04/14 ~ 04/15, 전경련회관) |
| 권호 | 30권 1호, p.287 |
| 발표분야 | 분자전자 부문위원회 |
| 제목 | Novel Naked-Eye Colorimetric Sensing and Chromogenic Imaging of Poly(ortho-phenylazonaphthol) Derivatives |
| 초록 | The chromogenic derivatives sensitive to many different stimuli can be produced which might attract interest in imaging, data storage, and sensing applications. A new series of copolymers containing ortho-phenylazonaphthol group were synthesized to apply to chromogenic imaging and colorimetric sensing. We will describe the novel color imaging properties in the solid state using protection and deprotection of t-Boc groups in the polymer backbone. The polymers with free hydroxyl groups resulted from deprotection of t-Boc groups exhibited considerable red-shift compared to t-Boc-protected polymers. We performed color-patterning using different colors before ( λmax = 341 nm, yellow ) and after deprotection ( λmax = 523 nm, violet ) of t-Boc from the polymers. Furthermore, we performed colorimetric anion sensing based on the keto-enol tautomerism of free hydroxyl groups in polymer backbone resulting in naked-eye color change. 그림 1. Thermo-labile chromogenic polymers |
| 저자 | 최문수, 김형준, 이택승 |
| 소속 | 충남대 |
| 키워드 | chromogenic sensing; chromogenic patterning; ortho-phenylazonaphthol polymer; anion sensor |
